Kayayyaki

(3R,4S,5R,6R) -3,4,5-tris (triMethylsilyloxy) -6-((triMethylsilyloxy)Methyl) tetrahydro-2H-pyran-2-daya, wanda kuma aka sani da TBDMS-kare tetrahydro-2H-pyran -2-one, wani fili ne da aka saba amfani da shi wajen hada kwayoyin halitta kuma a matsayin kungiyar karewa a fagen ilmin sinadarai.Daya daga cikin muhimman aikace-aikace na tetrahydro-2H-pyran-2-kare TBDMS-daya shine amfani da shi azaman toshe ginin a cikin haɗin. na hadadden kwayoyin halitta.Filin yana da rukunoni masu amsawa da yawa waɗanda zasu iya jurewa canje-canjen ƙungiyoyin ayyuka daban-daban.Ƙungiyar kare TBDMS (tert-butyldimethylsilyl) da ke cikin kwayar halitta tana ba da kwanciyar hankali kuma yana ba da damar gyare-gyare na musamman na ƙungiyoyi masu aiki.Wannan juzu'i yana sa TBDMS-kare tetrahydro-2H-pyran-2-daya zama matsakaici mai mahimmanci a cikin haɗin samfuran halitta, magunguna, da sauran sinadarai masu kyau. rawar a matsayin ƙungiyar kariyar ga barasa da amines a cikin haɗin gwiwar kwayoyin halitta.Ƙungiyar TBDMS za a iya zaɓin ƙara zuwa ƙungiyoyin hydroxyl ko amino, yadda ya kamata a rufe su yayin matakai daban-daban.Wannan kariyar yana hana abubuwan da ba'a so ba kuma yana tabbatar da canjin da ake so ya faru a wuraren da ake so.Da zarar halayen da ake so sun cika, ƙungiyar TBDMS za a iya cire su cikin sauƙi, suna fallasa asalin hydroxyl ko rukunin amino ba tare da shafar wasu ayyuka a cikin kwayoyin ba.TBDMS-kare tetrahydro-2H-pyran-2-wanda kuma ya sami aikace-aikacen azaman wakili mai karewa don carbohydrates.Yana ba da izinin zaɓin kariya na ƙungiyoyin hydroxyl a cikin ƙwayoyin sukari yayin halayen glycosylation, yana ba da damar haɓakar hadaddun glycans da glycosides.Wannan dabarun kariya yana da mahimmanci musamman a cikin sunadarai na carbohydrate, inda ƙungiyoyin hydroxyl da yawa suke kasancewa kuma ana buƙatar takamaiman regioselectivity.Bugu da ƙari, TBDMS-kare tetrahydro-2H-pyran-2-one ana amfani dashi a cikin shirye-shiryen polymers masu aiki.Ana iya shigar da fili cikin sifofin polymer, yana samar da wuraren da za a iya ɗauka don ƙarin gyare-gyare da halayen haɗin kai.Wannan yana ba da damar ƙirƙirar kayan polymer tare da kaddarorin da aka keɓance da ayyuka, irin su ingantaccen kwanciyar hankali, daidaitawa, da sakin magunguna. -((triMethylsilyloxy) Methyl) tetrahydro-2H-pyran-2-daya, ko TBDMS-kare tetrahydro-2H-pyran-2-one, wani m fili tare da daban-daban aikace-aikace a cikin kwayoyin kira, musamman a matsayin ginin block da kuma kare kungiyar. .Ƙarfinsa na zaɓin kare ƙungiyoyi masu aiki da sauƙaƙe rikitattun sauye-sauyen ƙwayoyin cuta ya sa ya zama kayan aiki mai mahimmanci a fagen ilmin sunadarai.Ci gaba da bincike da bincika aikace-aikacen sa na iya buɗe ƙarin amfani da ba da gudummawa ga ci gaba a cikin sinadarai na roba da kimiyyar kayan aiki.