Pentamethylcyclopentadienyltris (acetonitrile) ruthenium (II) hexafluorophosphate Cas: 99604-67-8 Yellow Orange Foda
| Lambar Catalog | Saukewa: XD90827 |
| Sunan samfur | Pentamethylcyclopentadienyltris (acetonitrile) ruthenium (II) hexafluorophosphate |
| CAS | 99604-67-8 |
| Tsarin kwayoyin halitta | Saukewa: C16H24F6N3PRU |
| Nauyin Kwayoyin Halitta | 504.42 |
| Bayanin Ajiya | 2-8 ° C |
Ƙayyadaddun samfur
| Bayyanar | Yellow Orange Foda |
| Assay | 99% |
Ana nuna hadaddun [Cp * Ru(MeCN)3] PF6 don kunna hydrosilylation na kewayon alkynes.Terminal alkynes yana ba da damar yin amfani da samfuran alpha-vinylsilane tare da kyakkyawan zaɓi na regioselectivity.Nazarin lakabin Deuterium yana nuna tsarin ƙari mai tsabta yana kan aiki.Irin wannan hadaddun yana aiki a cikin alkyne hydrosilylation na ciki, inda ake kiyaye cikakken zaɓi don tsarin ƙari na trans.Yawancin azuzuwan substrate na ciki, gami da propargylic alcohols da alpha, mahadi na beta-alkynyl carbonyl, suna ba da izinin samuwar vinylsilane regioselective.Haƙuri da kewayon silanes da yawa abin lura ne, gami da alkyl-, aryl-, alkoxy-, da halosilanes.Ana nuna wannan fa'idar a cikin haɗin kai tsaye na kayan aikin triene don cycloadditions na Diels-Alder intramolecular silicon-tethered.
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