Kayayyaki

Ana amfani da ƙayyadaddun ƙayyadaddun rawar jiki sau uku don haɗawa da mahaɗar yanayi don lura da canjin daidaituwar girgiza tsakanin yanayin asymmetric da daidaitawa CO-miƙewa na rhodium(I) dicarbonyl acetylacetonate (RDC).Canja wurin haɗin kai shine sauyi mara haske na madaidaicin matsayi na juzu'i na juzu'i zuwa wani madaidaicin matsayi na daban saboda haɗuwa da yanayin girgiza ta cikin wanka.Duk nau'ikan motsa jiki guda uku a cikin gwajin suna da ƙarfi tare da daidaituwar adadi guda ɗaya, amma canja wurin haɗin gwiwa yana haifar da sabbin haɗin kai tare da mitoci daban-daban.Ana lura da sabon mitar fitarwa tare da monochromator wanda ke warware shi daga mafi ƙarfi a mitar tashin hankali na asali.Wannan dabarar a kaikaice tana warware hanyoyin da suka haɗa da canja wurin haɗin gwiwa, suna nuna wariya ga fasalulluka waɗanda aka ƙirƙira ta hanyar sauye-sauye masu haske, kuma na ɗan lokaci yana warware gyare-gyaren da aka ƙirƙira ta hanyar tsangwama tsakanin hanyoyin canja wuri daban-daban.Ka'idar Redfield tana jinkirta gyare-gyare na ɗan lokaci a cikin ƙayyadaddun ƙayyadaddun sha'awa, amma kuma a fili yake cewa canja wurin haɗin kai ya saba wa ƙima na duniya da aka kira a yawancin ka'idodin Redfield.Madadin haka, yana buƙatar waɗanda ba na Markova da tasirin ƙwaƙwalwar wanka ba.RDC na iya samar da samfuri mai sauƙi don haɓaka ra'ayoyin da suka haɗa waɗannan tasirin.